__ sapiens

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Last seen on: –LA Times Crossword 6 May 21, Thursday
LA Times Crossword 14 Jul 20, Tuesday

Random information on the term “__ sapiens”:

Berengar, called the Wise (Catalan: Berenguer el Savi, Latin: Berengarius Sapiens), was the count (or duke) of Toulouse (814–835) and duke (or margrave) of Septimania (832–835). He held the County of Barcelona concomitantly with Septimania.

Berengar was a member of the family of the Unrochids. He was the son of Unruoch II of Friuli and Ingeltrude and brother of Eberhard. His nephew was the Holy Roman Emperor Berengar.

In 814, Louis the Pious installed Berengar as Count of Toulouse in succession to Raymond Raphinel who had been appointed by Charlemagne. He was also a councillor of Pepin I of Aquitaine in 816. In 819, he and Guerin, Count of Auvergne, fought against the usurping Duke of Gascony, Lupo III Centule. Berengar appears as a missus dominicus of Louis in May 825 and then in 827 in the six counties of Rheims, Soissons, Senlis, Beauvais, Laon, and Catolonis and the four bishoprics of Amiens, Cambrai, Saint-Pol-sur-Ternoise, and Noviomacensem.

In November 831, Pepin revolted against his father, with Berengar advising him not to rebel, but with Bernard of Septimania inciting him. In the beginning of 832, Louis the Pious began campaigning against his rebellious son. Berengar, loyal to the Emperor, attacked the domains of Bernard, taking Roussillon (with Vallespir), Razès, and Conflent. On 2 February, Berengar had already reached Elna. Finally, in the autumn of the same year, successive victories by the imperial forces compelled Pepin and Bernard to appear before the Emperor (October) to plead for peace. Pepin was dispossessed of his kingdom and sent, as a prisoner, to Trier. His territories were given to Charles the Bald, youngest son of the Emperor. Bernard was accused of infidelity and dispossessed of all his lands in Septimania and Gothia; they were given to Berengar. Gaucelm, Bernard’s brother, was also dispossessed of the majority of his lands, but for a time kept the Empúries although this too was lost to Berengar later.

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Random information on the term “HOMO”:

In organic chemistry, the Diels–Alder reaction is a chemical reaction between a conjugated diene and a substituted alkene, commonly termed the dienophile (also spelled dieneophile), to form a substituted cyclohexene derivative. It is the prototypical example of a pericyclic reaction with a concerted mechanism. More specifically, it is classified as a thermally-allowed [4+2] cycloaddition with Woodward–Hoffmann symbol [π4s + π2s]. It was first described by Otto Diels and Kurt Alder in 1928. For the discovery of this reaction, they were awarded the Nobel Prize in Chemistry in 1950. Through the simultaneous construction of two new carbon–carbon bonds, the Diels–Alder reaction provides a reliable way to form six-membered rings with good control over the regio- and stereochemical outcomes. Consequently, it has served as a powerful and widely applied tool for the introduction of chemical complexity in the synthesis of natural products and new materials. The underlying concept has also been applied to π-systems involving heteroatoms, such as carbonyls and imines, which furnish the corresponding heterocycles; this variant is known as the hetero-Diels–Alder reaction. The reaction has also been generalized to other ring sizes, although none of these generalizations have matched the formation of six-membered rings in terms of scope or versatility. Because of the negative values of ΔH° and ΔS° for a typical Diels–Alder reaction, the microscopic reverse of a Diels–Alder reactions becomes favorable at high temperatures, although this is of synthetic importance for only a limited range of Diels-Alder adducts, generally with some special structural features; this reverse reaction is known as the retro-Diels–Alder reaction.

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