Grp. that extends from Canada to Chile

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it’s A 38 letters crossword definition.
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Possible Answers:

OAS.

Last seen on: NY Times Crossword 22 Nov 21, Monday

Random information on the term “OAS”:

O-Acetylserine is an α-amino acid with the chemical formula HO2CCH(NH2)CH2OC(O)CH3. It is an intermediate in the biosynthesis of the common amino acid cysteine in bacteria and plants. O-Acetylserine is biosynthesized by acetylation of the serine by the enzyme serine transacetylase. The enzyme O-acetylserine (thiol)-lyase, using sulfide sources, converts this ester into cysteine, releasing acetate:

OAS on Wikipedia